High CO2 permeability in supported molten-salt membranes with highly dense and aligned pores produced by directional solidification
نویسندگان
چکیده
Composite molten salt-ceramic membranes are promising devices for high-temperature CO2 separation. Intensive material properties impact on separation performance as do membrane geometry (thickness) and microstructure (pore volume fraction, size, connectivity, tortuosity factor). Although controlling pore size is considered somewhat routine, achieving alignment connectivity still challenging. Here we report the production of first gas using a porous ceramic matrix obtained from directionally-solidified magnesium-stabilised zirconia (MgSZ) – MgO fibrilar eutectic support. was removed parent by acid-etching to create with highly aligned pores diameters ~1 ?m. X-ray nano-computed tomography central portion (~32,000 ?m3) support identified ~21% porosity, all within 10° ~76% percolating along longest sampled length. Employing carbonate salt, high permeability 1.41x10-10 mol m-1.s-1.Pa-1 at 815 °C achieved, among highest reported supported molten-carbonate (typically 10-12 10-10 similar temperatures). We suggest that attributable excellent characteristics resulting directional solidification, namely dense array parallel, micron-scale connecting feed permeate sides membrane.
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ژورنال
عنوان ژورنال: Journal of Membrane Science
سال: 2021
ISSN: ['1873-3123', '0376-7388']
DOI: https://doi.org/10.1016/j.memsci.2021.119057